Armory play Bate Borisov of Belarus, while Chelsea – who won the opposition in 2013 – go up against Swedish side Malmo.
A large portion of the two-legged ties will be played on the 14 and 21 February 2019.
Armory's home second leg will be on Wednesday, 20 February at 17:00 GMT.
The Gunners and Chelsea were both seeded for the draw, which means they have their second legs and groups from a similar city can't play at home on that night.
The planning of the apparatus is to keep away from a conflict with the Champions League amusements occurring later on that Wednesday.
Weapons store and Chelsea both completed best of their separate gatherings, each triumphant five and drawing one of their six matches.
The Gunners are confronting a similar adversary they met in the gathering phase of last season's opposition, winning twice – 4-2 in Belarus and 6-0 in London.
Europa League last-32 draw in full
Viktoria Plzen v Dinamo Zagreb
Club Brugge v Red Bull Salzburg
Rapid Vienna v Inter Milan
Slavia Prague v Genk
Krasnodar v Bayer Leverkusen
FC Zurich v Napoli
Malmo v Chelsea
Shakhtar Donetsk v Eintracht Frankfurt
Celtic v Valencia
Rennes v Real Betis
Olympiakos v Dinamo Kiev
Lazio v Sevilla
Fenerbache v Zenit St Petersburg
Sporting Lisbon v Villarreal
Bate Borisov v Arsenal
Galatasaray v Benfica
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